No.
For a couple reasons:
1. We need to exercise the underlying ranking system to get the bugs out.
2. While the time before matching will increase as we ship, we do want to have the AI personalities in the ranking system to better tell where they themselves match up.
3. As a practical matter, once you get to a certain level (i.e. if you're good enough) you won't/can't be matched with AI as you will have gotten to good.
There were a lot of bugs in the first go of this which are being fixed (and should have been fixed in the latest update).